Deuterium fractionation on interstellar grains studied with the direct master equation approach     

Tatiana Stantcheva  Eric Herbst 《Monthly notices of the Royal Astronomical Society》2003,340(3):983-988

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Multiple longshore sand bars in the upper Chesapeake Bay     

Thomas J. Dolan  Robert G. Dean 《Estuarine, Coastal and Shelf Science》1985,21(5):727-743

In the upper Chesapeake Bay (Maryland, U.S.A.) field surveys were conducted at 18 multiple longshore sand bar sites. The multiple bar systems were found in water depths less than approximately 2 m (mean sea level), and exhibited mild bottom slopes of 0·0052 or less. The number of bars composing each system ranged from four to 17 and the spacing between the crests typically increased in the offshore direction, ranging from 12 to 70 m. Bar height also typically increased with distance offshore and ranged from 0·03 to 0·61 m. A grain size analysis of crest and trough sediment did not reveal any significant differences and the sediment was categorized as ‘fine sand’. A review of the literature data indicated that the Chesapeake Bay multiple bars possessed similar characteristics to those found in Gelding Bay (Baltic Sea); similarities in fetch, wave height and tidal range between the two bays may account for this finding. The surf-scaling parameter indicated that the multiple bar systems were extremely dissipative with regard to wave energy, and wave height appeared to be an important factor in controlling bar spacing and bar height. A multiple wave break point hypothesis was discussed as a possible mechanism for the formation of Chesapeake Bay multiple longshore bars, and limited observational evidence appeared to support such a mechanism.  相似文献   

Theoretical and experimental lifetime and oscillator strength determination in singly ionized neodymium (Nd ii)     

H. L. Xu  S. Svanberg  R. D. Cowan  P.-H. Lefèbvre  P. Quinet  E. Biémont 《Monthly notices of the Royal Astronomical Society》2003,346(2):433-440

Radiative lifetime measurements were performed with time-resolved laser-induced fluorescence techniques for 24 levels of Nd  ii in the energy range 20 500–32 500 cm⁻¹. For 17 levels, no previous experimental data exist. These results have allowed the testing of new theoretical calculations with the relativistic Hartree–Fock method taking configuration interactions and core-polarization effects into account, and a satisfying agreement has been found for this complex ion. A new set of calculated oscillator strengths, accurate within a few per cent for the strongest transitions, is presented for 107 lines of astrophysical interest appearing in the wavelength range 358.0–1100.0 nm. These results will be useful to evaluate abundance values of neodymium in chemically peculiar stars in relation with cosmochronology.  相似文献   

Laboratory studies of the interaction of carbon monoxide with water ice     

M.P. Collings  J.W. Dever  H.J. Fraser  M.R.S. McCoustra 《Astrophysics and Space Science》2003,285(3-4):633-659

The interaction of carbon monoxide (CO) with vapour-deposited water(H₂O) ices has been studied using temperature programmed desorption (TPD) and Fourier transform reflection-absorption infrared spectroscopy (FT-RAIRS) over a range of astrophysically relevant temperatures. Such measurements have shown that CO desorption from amorphous H₂Oices is a much more complex process than current astrochemical models suggest. Re-visiting previously reported laboratory experiments (Collings et al., 2003), a rate model has been constructed to explain, in a phenomenological manner, the desorption of CO over astronomically relevant time scales. The model presented here can be widely applied to a range of astronomical environments where depletion of CO from the gas phase is relevant. The model accounts for the two competing processes of CO desorption and migration, and also enables the entrapment of some of the CO in the ice matrix and its subsequent release as the water ice crystallises and then desorbs. The astronomical implications of this model are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Outflow channel sources, reactivation, and chaos formation, Xanthe Terra, Mars     

Jose A.P. Rodriguez  Sho Sasaki  James M. Dohm  Hideaki Miyamoto  Goro Komatsu  Justin C. Ferris 《Icarus》2005,175(1):36-57

The undulating, warped, and densely fractured surfaces of highland regions east of Valles Marineris (located north of the eastern Aureum Chaos, east of the Hydraotes Chaos, and south of the Hydaspis Chaos) resulted from extensional surface warping related to ground subsidence, caused when pressurized water confined in subterranean caverns was released to the surface. Water emanations formed crater lakes and resulted in channeling episodes involved in the excavation of Ares, Tiu, and Simud Valles of the eastern part of the circum-Chryse outflow channel system. Progressive surface subsidence and associated reduction of the subsurface cavernous volume, and/or episodes of magmatic-driven activity, led to increases of the hydrostatic pressure, resulting in reactivation of both catastrophic and non-catastrophic outflow activity. Ancient cratered highland and basin materials that underwent large-scale subsidence grade into densely fractured terrains. Collapse of rock materials in these regions resulted in the formation of chaotic terrains, which occur in and near the headwaters of the eastern circum-Chryse outflow channels. The deepest chaotic terrain in the Hydaspis Chaos region resulted from the collapse of pre-existing outflow channel floors. The release of volatiles and related collapse may have included water emanations not necessarily linked to catastrophic outflow. Basal warming related to dike intrusions, thermokarst activity involving wet sediments and/or dissected ice-enriched country rock, permafrost exposed to the atmosphere by extensional tectonism and channel incision, and/or the injection of water into porous floor material, may have enhanced outflow channel floor instability and subsequent collapse. In addition to the possible genetic linkage to outflow channel development dating back to at least the Late Noachian, clear disruption of impact craters with pristine ejecta blankets and rims, as well as preservation of fine tectonic fabrics, suggest that plateau subsidence and chaos formation may have continued well into the Amazonian Period. The geologic and paleohydrologic histories presented here have important implications, as new mechanisms for outflow channel formation and other fluvial activity are described, and new reactivation mechanisms are proposed for the origin of chaotic terrain as contributors to flooding. Detailed geomorphic analysis indicates that subterranean caverns may have been exposed during chaos formation, and thus chaotic terrains mark prime locations for future geologic, hydrologic, and possible astrobiologic exploration.  相似文献   

The importance of new rate coefficients for deuterium fractionation reactions in interstellar chemistry     

Helen Roberts  Eric Herbst  T. J. Millar 《Monthly notices of the Royal Astronomical Society》2002,336(1):283-290

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Effective collision strengths with inclusion of resonance for hyperfine-structure transitions in H- and Li-like ions     

Hong Lin Zhang  Douglas H. Sampson 《Monthly notices of the Royal Astronomical Society》2001,322(3):433-437

Calculations are made of the resonance contribution to electron-impact excitation of H-like ¹³C and Li-like ²³Na, ²⁵Mg, ²⁷Al and ²⁹Si to the upper hyperfine levels that produce millimetre (mm) lines of likely astrophysical interest. The resonance contribution is found to be very important for these Li-like ions, considerably more important than for Li-like ⁵⁷Fe considered previously. However, resonances are found to be rather unimportant for H-like ¹³C. The effect of radiative decay on the resonance contribution is found to be insignificant in all of the present calculations.  相似文献   

On water ice formation in interstellar clouds     

R. Papoular 《Monthly notices of the Royal Astronomical Society》2005,362(2):489-497

A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol⁻¹, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ₃( A _v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.  相似文献   

Fragmentation and the formation of primordial protostars: the possible role of collision-induced emission     

E. Ripamonti  T. Abel 《Monthly notices of the Royal Astronomical Society》2004,348(3):1019-1034

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Detection of rovibrationally excited H2 formed through the heterogeneous recombination of H atoms on a cold HOPG surface     

J.S.A. Perry  S.D. Price 《Astrophysics and Space Science》2003,285(3-4):769-776

This paper reports results from an experiment designed to measure the nascent rovibrational population of H₂ molecules that have formed through the heterogeneous recombination of H atoms on the surface of cosmic dust analogues under conditions approaching those of the interstellar medium (ISM). H₂ that has formed on a highly oriented pyrolytic graphite (HOPG) surface has been detected, using laser induced resonance-enhanced multi-photon ionization (REMPI), in the v = 1 (J= 0–3) rovibrational states at surface temperatures of 30 K and 50 K. These excited product molecules display rotational temperatures significantly higher than the target surface temperature. These first results suggest that a considerable proportion of the binding energy released on formation of the H₂ is deposited in the surface, in addition to internal excitation of the product molecules. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献